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Enrichment in saturated compounds of Black Sea interfacial sediment

Abstract

THE sediment/water interface of the ocean should consist of organic compounds produced both in the overlying water column and during early diagenesis1–5. We have found that the uppermost 1 mm of sediment samples obtained from the Black Sea are enriched in saturated sterols and fatty acids relative to both suspended particles and underlying sediments. We speculate that either this 'floc' layer contains a microbial community capable of yielding a distribution of compounds that is high in saturated species, or the floe accumulates low-density, fine material enriched in saturated components produced in the water column6. Saturated components would thus be formed or concentrated very early during sedimentation and diagenesis. This has important implications for hydrogenation rates in geological environments, and may cast light on the way in which biological materials, rich in unsaturated compounds, become converted into sediments, petroleum and source rocks that contain predominantly saturated compounds.

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Beier, J., Wakeham, S., Pilskaln, C. et al. Enrichment in saturated compounds of Black Sea interfacial sediment. Nature 351, 642–644 (1991). https://doi.org/10.1038/351642a0

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