Skip to main content
SpringerLink
Log in

Isotherms and heats of adsorption of neopentane and carbon tetra chloride vapor on graphitized carbon black

  • Inorganic and Analytical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Measurements have been made of the adsorption isotherms and differential heat of adsorption of neopentane and carbon tetrachloride on thermal black graphitized at 3000°.

  2. 2.

    The large sphere-like molecules of these substances are adsorbed in a predominantly nonlocalized way, and interact strongly with one another, which causes a marked increase in the heat of adsorption as the monolayer is being filled and a strongly concave initial portion of the adsorption isotherm.

  3. 3.

    Free rotations or rotational oscillations of these molecules are possible in the adsorbed layer with small amounts of surface filling.

  4. 4.

    A discussion is given of different possible ways of defining the standard state of the adsorbed layer on a homogeneous surface, and values are given for the corresponding thermodynamic quantities of the adsorptive systems studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. V. Kiselev, Zh. fiz. khimii35, 233 (1961).

    Google Scholar 

  2. A. V. Kiselev, Quart Rev.15, 99 (1961).

    Google Scholar 

  3. R. A. Beebe, G. L. Kington, M. H. Polly, and W. R. Smith, J. Amer. Chem. Soc.72, 40 (1950).

    Google Scholar 

  4. N. N. Avgul', G. I. Berezin, A. V. Kiselev, and I. A. Lygina, Izv. AN SSSR Otd, khim. n. 1961, 205; N. N. Avgul', A. V. Kiselev, and I. A. Lygina, Kolloidn. zh.23, 369, 513 (1961).

  5. A. A. Isirikyan, and A. V. Kiselev, Kolloidn. zh.23, 281 (1961); J. Phys. Chem.65, 601 (1961); A. V. Kiselev and E. V. Khrapova, Kolloidn. zh.,23, 163 (1961).

    Google Scholar 

  6. N. N. Avgul', G. I. Berezin, A. V. Kiselev, I. A. Lygina, and G. G. Muttik, Zh. fiz. khimii31, 111 (1957).

    Google Scholar 

  7. S. Brunauer, H. Emmett, and E. Teller, J. Amer. Chem. Soc.60, 309 (1938).

    Google Scholar 

  8. Landolt-Börnstein, Tabellen, 6 Aufl., 1 Bd., 2 Teil. S. 4–23 (1951).

  9. Landolt-Börnstein, Tabellen, 6 Aufl., 1 Bd., 4 Teil., S. 531–533 (1951).

  10. N. N. Avgul' G. I. Berezin, A. V. Kiselev, and I. A. Lygina, Izv. AN SSSR, Otd. khim. n. 1959, 787.

  11. A. V. Kiselev, Kolloidn. zh.20, 338 (1958); A. V. Kiselev and D. P. Poshkus, Izv. AN SSSR, Otd. khim. n. 1958, 520.

  12. T. Hill, J. Chem. Phys.14, 441 (1946).

    Google Scholar 

  13. S. Ross and W. Winkler, J. Coll. Sci.10, 319, 330 (1955).

    Google Scholar 

  14. N. N. Avgul', G. I. Berezin, I. A. Lygina, and A. V. Kiselev, Izv. AN SSSR, Otd. khim. n.1957, 1021.

  15. N. N. Avgul', A. A. Isirikyan, A. V. Kiselev, I. A. Lygina, and D. P. Poshkus, Izv. AN SSSR, Otd. khim. n.1957, 1314;1959, 1196.

  16. A. V. Kiselev and A. A. Isirikyan, Zh. fiz. khimii32, 679 (1958).

    Google Scholar 

  17. N. N. Avgul', A. V. Kiselev, and I. A. Lygina, Izv. AN SSSR, Otd. khim. n. (1962) (in press).

Download references

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences USSR, USSR

    N. N. Avgul', A. V. Kiselev, I. A. Lygina & E. A. Mikhailova

  2. N. D. Zelinskii Institute of Organic Chemistry, USSR

    N. N. Avgul', A. V. Kiselev, I. A. Lygina & E. A. Mikhailova

Authors
  1. N. N. Avgul'
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Kiselev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Lygina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. A. Mikhailova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

The authors express their gratitude to Z. S. Kraits for furnishing the purified carbon tetrachloride.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Avgul', N.N., Kiselev, A.V., Lygina, I.A. et al. Isotherms and heats of adsorption of neopentane and carbon tetra chloride vapor on graphitized carbon black. Russ Chem Bull 11, 717–723 (1962). https://doi.org/10.1007/BF00905289

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00905289

Keywords

Search

Navigation