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N-(α-ferrocenylalkyl) pyridinium salts

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    N- (α-Ferrocenylalkyl)pyridinium p-toluenesulfonates are formed when ferrocenylcarbinols are reacted with p-toluenesulfonyl chloride in pyridine.

  2. 2.

    The N-(α-ferrocenylalkyl)pyridinium salts are good ferrocenylalkylating agents. The exchange reaction of the N-(α-ferrocenylalkyl)pyridinium p-toluenesulfonates with NaCN gave the nitriles of ferrocenylacetic,α-ferrocenylpropionic and ferrocenyl(phenyl)aeetic acids.

  3. 3.

    The nitriles of the ferrocenylacetic andα-ferrocenylpropionic acids were hydrolyzed to the amides of the corresponding acids.

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Literature cited

  1. W. Borsche and E. Feske, Ber.,61, 698 (1928).

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  3. A. N. Nesmeyanov, V. A. Sazonova, V. N. Drozd, and N. A. Rodionova, DAN SSSR,160, 355 (1964).

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Authors and Affiliations

  1. M. V. Lomonosov State University, Moscow

    A. N. Nesmeyanov, E. G. Perevalova & M. D. Reshetova

Authors
  1. A. N. Nesmeyanov
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  2. E. G. Perevalova
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  3. M. D. Reshetova
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Nesmeyanov, A.N., Perevalova, E.G. & Reshetova, M.D. N-(α-ferrocenylalkyl) pyridinium salts. Russ Chem Bull 15, 301–303 (1966). https://doi.org/10.1007/BF00856060

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  • DOI: https://doi.org/10.1007/BF00856060

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