Conclusions
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1.
Diferrocenylacetonitrile was prepared from the hydrochloride of diferrocenylchloromethane and from N-(diferrocenylmethyl)pyridinium p-toluenesulfonate. Diferrocenylphenylacetonitrile was prepared from the hydrochloride of diferrocenylphenylchloromethane.
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2.
Triferrocenylcarbinol, under conditions normally leading to the formation of N-(ferrocenylalkyl)-pyridinium salts, decomposes to diferrocenylfulvene.
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3.
Diferrocenylacetonitrile is transformed into diferrocenyl ketone on aluminum oxide.
Literature cited
A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva, and O. F. Filippov, Izv. AN SSSR, Ser. khim.,1967, 464.
A. N. Nesmeyanov, É. G. Perevalova, and M. D. Reshetova, Izv. AN SSSR, Ser. khim.,1966, 335.
A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva, and Yu. A. Ustynyuk, Izv. AN SSSR, Ser. khim.,1966, 558.
A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva, and Yu. A. Ustynyuk, Izv. AN SSSR, Ser. khim.,1966, 556.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1617–1618, July, 1967.
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Perevalova, É.G., Leont'eva, L.I. & Reshetova, M.D. Diferrocenyl- and diferrocenylphenyl-acetonitriles. Russ Chem Bull 16, 1559–1560 (1967). https://doi.org/10.1007/BF00905376
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DOI: https://doi.org/10.1007/BF00905376