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Accuracy in the determination of thermodynamic solution functions from retention indexes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Equations are proposed for evaluating the accuracy in the determination of the relative distribution coefficients, separation factors, differences in partial molar enthalpies, entropies, and free energies of solution from retention indexes which give an error of the same order of magnitude as the gas-chromatographic method of determination from specific retention volumes.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 632–635, March, 1972.

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Golovnya, R.V., Arsen'ev, Y.N. & Kurganova, T.V. Accuracy in the determination of thermodynamic solution functions from retention indexes. Russ Chem Bull 21, 595–597 (1972). https://doi.org/10.1007/BF00863219

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  • DOI: https://doi.org/10.1007/BF00863219

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