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Telomerization of ethylene with acetonitrile and capronitrile

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The telomerization of ethylene with acetonitrile and capronitrile goes with a rearrangement of the radicals and a 1,5 migration of the hydrogen atom.

  2. 2.

    A measurement of the partial chain transfer constants and the relative isomerization constant in the telomerization of ethylene with acetonitrile revealed that the rearrangement goes to less degree in the given reaction than in the reactions of ethylene with methyl acetate, propionitrile, and methyl propionate.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. B. Terent'ev, M. A. Churilova, V. I. Dostovalova & V. A. Svoren'

Authors
  1. A. B. Terent'ev
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  2. M. A. Churilova
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  3. V. I. Dostovalova
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  4. V. A. Svoren'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1814–1818, August, 1974.

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Terent'ev, A.B., Churilova, M.A., Dostovalova, V.I. et al. Telomerization of ethylene with acetonitrile and capronitrile. Russ Chem Bull 23, 1732–1735 (1974). https://doi.org/10.1007/BF00923199

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  • DOI: https://doi.org/10.1007/BF00923199

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