Skip to main content
SpringerLink
Log in

Dual reactivity of electrochemically generated 2-thiophenaldehyde anion-radicals

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The one-electron reduction of 2-thiophenaldehyde in DMF as the medium gives, besides the usual dimerization product of the pinacol type, also 5-(α-thienyl)-2-acetoxymethylthiophenaldehyde, which is explained by the dual reactivity of the electrochemically generated anion-radicals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. C. K. Mann and K. K. Barnes, Electrochemical Reactions in Nonaqueous Systems, Marcel Dekker (1970).

  2. M. V. Tilborg and C. J. Smit, Tetrahedron Lett.,1977, 3651

  3. E. M. Abbot, A. J. Bellamy, and J. Kerr, Chem. Ind. (London),1974, 828.

  4. L. Horner and D. Degner, Tetrahedron Lett.,1971, 1241.

  5. C. Caullet, M. Salaun, and M. Hebert, Compt. Rend.,264C, 228 (1967).

    Google Scholar 

  6. P. Foulatier and C. Caullet, Compt. Rend.,279C, 25 (1974).

    Google Scholar 

  7. L. N. Vykhodtseva and L. N. Nekrasov, Elektrokhimiya,13, 1239 (1977).

    Google Scholar 

  8. V. P. Gul'tyai, S. G. Mairanovskii, T. Ya. Rubinskaya, I. V. Proskurovskaya, and N. P. Rodionov, Elektrokhimiya,15, 851 (1979).

    Google Scholar 

  9. V. P. Gul'tyai, L. M. Korotaeva, A. S. Mendkovich, and I. V. Proskurovskaya, Izv. Akad. Nauk SSSR, Ser. Khim.,1981, 834.

  10. A. Bewick and H. P. Cleghorn, J. Chem. Soc. Perkin Trans. 2,1973, 1410.

  11. V. P. Gul'tyai and A. M. Moiseenkov, Zh. Org. Khim.,16, 1026 (1980).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. P. Gul'tyai, L. M. Korotaeva, A. P. Rodionov & A. M. Moiseenkov

Authors
  1. V. P. Gul'tyai
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. M. Korotaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. P. Rodionov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. M. Moiseenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1150–1153, May, 1981.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gul'tyai, V.P., Korotaeva, L.M., Rodionov, A.P. et al. Dual reactivity of electrochemically generated 2-thiophenaldehyde anion-radicals. Russ Chem Bull 30, 911–913 (1981). https://doi.org/10.1007/BF00955316

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00955316

Keywords

Search

Navigation