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Applicability of a universal equation in capillary gc for calculating the retention indexes and boiling points of members of O-, N-, and S-containing homologous series

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The fundamental character of the universal equation proposed earlier for calculation of retention parameters of homologs in chromatography has been confirmed. It has been shown that the equation can be used with excellent results to calculate the boiling points of members of homologous series of organic compounds.

  2. 2.

    It has been demonstrated, using the example of 18 homologous series of organic compounds (alcohols, alkylamines, sulfides, mercaptans, nitroalkanes, isonitriles) that the equation can be correctly used to predict boiling points.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute for Organometallic Compounds, Academy of Sciences of the USSR, Moscow

    D. N. Grigor'eva, R. V. Golovnya, L. A. Semina & A. L. Samusenko

Authors
  1. D. N. Grigor'eva
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  2. R. V. Golovnya
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  3. L. A. Semina
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  4. A. L. Samusenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 301–306, February, 1989.

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Grigor'eva, D.N., Golovnya, R.V., Semina, L.A. et al. Applicability of a universal equation in capillary gc for calculating the retention indexes and boiling points of members of O-, N-, and S-containing homologous series. Russ Chem Bull 38, 254–259 (1989). https://doi.org/10.1007/BF00953608

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  • DOI: https://doi.org/10.1007/BF00953608

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