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Selective dimerization of vinyl ketones to 1,5-diketones, catalyzed by RhCl(PMe3)3

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A selective method has been developed for the synthesis of α-methylene-1,5-diketones by dimerization of vinyl ketones catalyzed by RhCl(PMe3)3. Aromatic vinyl ketones dimerize more readily than aliphatic vinyl ketones.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    I. P. Kovalev, Yu. N. Kolmogorov, A. V. Ignatenko, M. G. Vinogradov & G. I. Nikishin

Authors
  1. I. P. Kovalev
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  2. Yu. N. Kolmogorov
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  3. A. V. Ignatenko
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  4. M. G. Vinogradov
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  5. G. I. Nikishin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1098–1103, May, 1989.

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Kovalev, I.P., Kolmogorov, Y.N., Ignatenko, A.V. et al. Selective dimerization of vinyl ketones to 1,5-diketones, catalyzed by RhCl(PMe3)3 . Russ Chem Bull 38, 995–999 (1989). https://doi.org/10.1007/BF00955432

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  • DOI: https://doi.org/10.1007/BF00955432

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