Abstract
A new choice is proposed for the generating functional which is used to obtain an integral equation for the radial distribution function that is valid in the domain of dense fluids. The corresponding equation of state for giving the intramolecular potential in the form ϕ(r)∼r −s agrees in the case of dense fluids with the known Tait empirical equation of state. The Tait equation is extended to the high-pressure case. Processing the experimental data for water exhibits good agreement between the equation of state obtained and experiment in the pressure range from 105−109 Pa.
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 43–47, December, 1981.
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Sysoev, V.M., Chalyi, A.V. Equation of state of condensed media. Soviet Physics Journal 24, 1104–1108 (1981). https://doi.org/10.1007/BF00893734
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DOI: https://doi.org/10.1007/BF00893734