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Mössbauer study of the kinetics of simulated corrosion process of iron in chlorinated aqueous solution around room temperature: The hyperfine structure of ferrous hydroxides and Green Rust I

  • Lattice Dynamics, Relaxation, Phase Transitions
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Abstract

The hyperfine structure of the two ferrous hydroxides, Fe(OH)2, [2Fe(OH)2, FeOCl] and Green Rust I obtained during the oxidation of iron in chlorinated aqueous medium is determined. The structure of GRI is proposed. The kinetics of oxidation and the role of the chlorine concentration is thoroughly discussed.

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Authors and Affiliations

  1. L.S.M., Département Sciences des Matériaux, I.S.I.N., Université de Nancy I, 54500, Vandoevre-Nancy, France

    J. M. Genin, Ph. Bauer, A. A. Olowe & D. Rezel

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  1. J. M. Genin
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  2. Ph. Bauer
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  3. A. A. Olowe
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  4. D. Rezel
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Genin, J.M., Bauer, P., Olowe, A.A. et al. Mössbauer study of the kinetics of simulated corrosion process of iron in chlorinated aqueous solution around room temperature: The hyperfine structure of ferrous hydroxides and Green Rust I. Hyperfine Interact 29, 1355–1360 (1986). https://doi.org/10.1007/BF02399485

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  • DOI: https://doi.org/10.1007/BF02399485

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