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Interaction of aniline and benzidine with layered solids Mn+(UO2XO4) − n ·z H2O[M = H3O+, Cu2+, VO2+, Fe2+; X = P, As]

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Abstract

The layered acid solids of formula H3OUO2XO4· 3 H2O (X = As, P) intercalate aniline and benzidine arylamines, by protonation of the guest molecules. The intercalates maintain the original laminar structure.

The insertion of aniline and benzidinein the metal derivativesM(UO2XO4)2·n H2O (M = Cu, VO, Fe) requires rather drastic conditions. Near and medium infrared spectra of intercalates in which M = VO2+ and Cu2+, indicate that the polymerization and/or oxidation of sorbed amines occurs; however, the guest-host reactions for Fe2+-derivatives are of the acid-base type.

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References

  1. D. H. Solomon, B. C. Loft, and J. D. Swift:Clay Min. 7, 389 (1968).

    Google Scholar 

  2. P. Cloos, A. Moreale, C. Braers, and C. Badot:Clay Min. 14, 307 (1979).

    Google Scholar 

  3. H. Masbah, D. Tinet, M. Crespin, R. Erre, R. Setton, and H. Van Damme:J. Chem. Soc., Chem. Commun. 935 (1985).

  4. T. Farukawa and G. W. Brindley:Clays Clay Min. 21, 279 (1973).

    Google Scholar 

  5. F. Weigel and G. Hoffman:J. Less. Comm. Metals 44, 99 (1970).

    Google Scholar 

  6. L. Moreno Real, R. Pozas Tormo, M. Martínez Lara, and S. Bruque:Mat. Res. Bull. 22, 19 (1987).

    Google Scholar 

  7. R. Pozas Tormo, L. Moreno Real, M. Martínez Lara, and S. Bruque:Can. J. Chem. 64, 30 (1985).

    Google Scholar 

  8. A. T. Howe and M. G. Shilton:J. Solid State Chem. 28, 345 (1979), and31, 393 (1979).

    Google Scholar 

  9. M. Martínez Lara, A. Jimenez Lopez, L. Moreno Real, S. Bruque, B. Casal, and E. Ruiz-Hitzky:Mat. Res. Bull. 20, 549 (1985).

    Google Scholar 

  10. M. Raupach and L. J. Janik:J. Colloid Interface Sci. 121, 449 (1988).

    Google Scholar 

  11. P. G. Slade and M. Raupach:Clays Clay. Min. 30, 297 (1982).

    Google Scholar 

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Authors and Affiliations

  1. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Malaga, Apartado 59, 29071, Malaga, Spain

    Maria Martinez-Lara, Jose A. Barea-Aranda, Laureano-Moreno Real & Sebastian Bruque

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  1. Maria Martinez-Lara
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  2. Jose A. Barea-Aranda
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  3. Laureano-Moreno Real
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  4. Sebastian Bruque
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Martinez-Lara, M., Barea-Aranda, J.A., Real, LM. et al. Interaction of aniline and benzidine with layered solids Mn+(UO2XO4) − n ·z H2O[M = H3O+, Cu2+, VO2+, Fe2+; X = P, As]. J Incl Phenom Macrocycl Chem 9, 287–299 (1990). https://doi.org/10.1007/BF01033308

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  • DOI: https://doi.org/10.1007/BF01033308

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