Skip to main content
SpringerLink
Log in

Mg-Zn-Al-CO3 and Zn-Cu-Al-CO3 hydrotalcite-like compounds: Preparation and characterization

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

A series ofM-Zn-Al (M=Mg, Cu) double hydroxide phases with carbonate anion were prepared by coprecipitation of 333 K, from the corresponding nitrate solution and sodium carbonate aqueous solution at pH 10. The characterization and properties of the products were investigated. It seems that reactivity of aluminium ions into the host layer depends on the identity of coexistent divalent cations (magnesium or copper), and the thermal properties of this layer at relatively high temperatures also depend on the nature of divalent cations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. C. Gastuche, G. Brown andM. M. Mortland,Clay Miner. 7 (1967) 177.

    Google Scholar 

  2. R. Allmann,Chimica 24 (1970) 99.

    Google Scholar 

  3. S. Miyata,Clays & Clay Miner. 23 (1975) 369.

    Google Scholar 

  4. F. Thevenot, R. Szymanski andP. Chaumette,ibid. 37 (1989) 396.

    Google Scholar 

  5. C. J. Serna, J. L. Rendon andJ. E. Iglesias,ibid. 30 (1982) 180.

    Google Scholar 

  6. R. Allmann,Acta Crystallogr. B24 (1968) 972.

    Google Scholar 

  7. H. F. W. Taylor,Miner. Mag. 37 (1969) 338.

    Google Scholar 

  8. W. T. Reichle,Chem. Technol. January16 (1986) 58.

    Google Scholar 

  9. F. Cavani, F. Trifiro andA. Vaccari,Catal. Today 11 (1991) 173.

    Google Scholar 

  10. F. Kooli, K. Kosuge, T. Hibino andA. Tsunashima,J. Mater. Sci. 28 (1993) 2769.

    Google Scholar 

  11. G. W. Brindley andS. Kikkawa.Am. Mineral. 64 (1979) 836.

    Google Scholar 

  12. E. B. M. Doesburg, R. H. Hoppener, B. De Koning, Xu. Xiao Ding andJ. J. F. Scholten, “Preparation of Catalysis IV”, edited by B. Delmon, P. Grange, P. A. Jacobs and G. Pancelet (Elsevier, Amsterdam, 1987) pp. 767.

    Google Scholar 

  13. K. Hashi, S. Kikkawa andM. Koizumi,Clays & Clay Miner. 31 (1983) 152.

    Google Scholar 

  14. C. Busetto, G. Del Piero, G. Manara, F. Trifiro andA. Vaccari,J. Catal. 85 (1984) 260.

    Google Scholar 

  15. L. Pausch, H. Lohse, K. Schurmann andR. Allmann,Clays & Clay Miner. 34 (1986) 507.

    Google Scholar 

  16. G. Brown andM. C. Castuche,Miner. Mag. 36 (1967) 193.

    Google Scholar 

  17. G. Mascolo andO. Marino,ibid. 43 (1980) 619.

    Google Scholar 

  18. R. D. Shannon,Acta Crystallogr. A32 (1976) 751.

    Google Scholar 

  19. F. M. Labajos, V. Rives andM. A. Ulibarri,Spectrosc. Lett. 24 (1991) 499.

    Google Scholar 

  20. P. C. Rouxhet andH. F. W. Taylor,Chimica 23 (1959) 480.

    Google Scholar 

  21. T. Sato, H. Fujita, T. Endo, M. Shimada andA. Tsunashima,Reactivity Solids 5 (1988) 219.

    Google Scholar 

  22. C. W. Beck,Am. Mineral. 35 (1950) 1006.

    Google Scholar 

  23. M. J. Hernandez-Moreno, M. A. Ulibarri, J. L. Rendon andC. J. Serna,Phys. Chem. Miner. 12 (1985) 34.

    Google Scholar 

  24. D. L. Bish andG. W. Brindley,Am. Mineral. 62 (1977) 458.

    Google Scholar 

  25. D. L. Bish,Bull. Mineral. 103 (1980) 170.

    Google Scholar 

  26. P. Tarte,Spectrochim. Acta 23A (1967) 2127.

    Google Scholar 

Download references

Author information

Author notes

  1. F. Kooli

    Present address: Department of Chemistry, University of Cambridge, Lensfield Road, CB2 1EW, Cambridge, UK

Authors and Affiliations

  1. Materials Processing Department, National Institute for Resources and Environment, 16-3 Onogawa, 305, Tsukuba, Japan

    F. Kooli, K. Kosuge & A. Tsunashima

Authors
  1. F. Kooli
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Kosuge
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Tsunashima
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kooli, F., Kosuge, K. & Tsunashima, A. Mg-Zn-Al-CO3 and Zn-Cu-Al-CO3 hydrotalcite-like compounds: Preparation and characterization. J Mater Sci 30, 4591–4597 (1995). https://doi.org/10.1007/BF01153066

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01153066

Keywords

Search

Navigation