Skip to main content
Log in

Topology of potential hypersurfaces of two, three and four dipoles interacting at long distances

  • Published:
Journal of Mathematical Chemistry Aims and scope Submit manuscript

Abstract

The whole sets of critical points of analytical functions corresponding to the long‐range two‐body interaction between two, three and four dipole vectors set at the vertices of several polygons are determined using topology theorems. Betti numbers associated to the configuration spaces are first obtained, then stationary points are located via an analytical gradient method till the Morse inequalities are checked.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R.G.A. Bone, T.W. Rowlands, N.C. Handy and A.J. Stone, Mol. Phys. 72 (1991) 33.

    Article  CAS  Google Scholar 

  2. J.G.C.M. van Duijneveldt-van de Rijdt and F.B. van Duijneveldt, Chem. Phys. Lett. 237 (1995) 560.

    Article  CAS  Google Scholar 

  3. M. Greenberg, in: Lectures on Algebraic Topology(Benjamin, New York, 1966).

    Google Scholar 

  4. W. Klopper and M. Schütz, Chem. Phys. Lett. 237 (1995) 536.

    Article  CAS  Google Scholar 

  5. D. Liotard, Thesis, Université de Pau, France (1979).

  6. D. Liotard and M. Rérat, Theoret. Chim. Acta 86 (1993) 297.

    Article  CAS  Google Scholar 

  7. S.A.C. McDowell, J. Chem. Phys. 105 (1996) 4180.

    Article  CAS  Google Scholar 

  8. P.G. Mezey, in: Potential Energy Hypersurfaces(Elsevier, New York, 1987).

    Google Scholar 

  9. O. Mó, M. Yañez and J. Elguero, J. Chem. Phys. 97 (1992) 6628.

    Article  Google Scholar 

  10. M. Morse, in: Calculus of Variation in the Large, Amer. Math. Colloq. Publ. 18 (1934).

  11. F. Pacella, Arch. Rat. Mech. Anal. 97 (1987) 59.

    Article  Google Scholar 

  12. M. Rérat and D. Liotard, J. Chim. Phys. 91 (1994) 1401.

    Google Scholar 

  13. M. Rérat, D. Liotard and J.M. Robine, Theoret. Chim. Acta 88 (1994) 285.

    Article  Google Scholar 

  14. M. Schütz, W. Klopper, H.P. Lüthi and S. Leutwyler, J. Chem. Phys. 103 (1995) 6114.

    Article  Google Scholar 

  15. E.G. Spanier, in: Algebraic Topology(McGraw-Hill, New York, 1966).

    Google Scholar 

  16. D.J. Wales and T.R. Walsh, J. Chem. Phys. 106 (1997) 7193.

    Article  CAS  Google Scholar 

  17. S. Wolfram, Mathematica: A System for Doing Mathematics by Computer, The Advanced Book Program (Addison-Wesley, Redwood City, CA, 1991).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rérat, M., Gélize, M. & Liotard, D. Topology of potential hypersurfaces of two, three and four dipoles interacting at long distances. Journal of Mathematical Chemistry 22, 235–247 (1997). https://doi.org/10.1023/A:1019136217083

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1019136217083

Keywords

Navigation