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Mössbauer spectroscopic studies of cubane-type clusters of [Mo3FeS4(NH3)9(H2O)]Cl4 and [Mo3FeS4(H2O)10](pts)4.7H2O (pts−: CH3(C6H4)SO −3 )

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Abstract

Mixed-metal cubane-type clusters of [Mo3FeS4(NH3)9(H2O)Cl4 and [Mo3FeS4(H2O)10](pts)4.7H2O have been characterized by means of57Fe-Mössbauer spectroscopy. The Mössbauer parameters indicate that the oxidation states of iron in the cluster compounds are ascribed to +2.54 and +2.39, respectively.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Fukasawa, Setagaya-ku, 158, Tokyo, Japan

    M. Katada & H. Sano

  2. Department of Chemistry, Okayama University of Science, 1-1 Ridal-cho, 700, Okayama, Japan

    H. Akashi & T. Shibahara

Authors
  1. M. Katada
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  2. H. Akashi
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  3. T. Shibahara
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  4. H. Sano
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Katada, M., Akashi, H., Shibahara, T. et al. Mössbauer spectroscopic studies of cubane-type clusters of [Mo3FeS4(NH3)9(H2O)]Cl4 and [Mo3FeS4(H2O)10](pts)4.7H2O (pts−: CH3(C6H4)SO −3 ). Journal of Radioanalytical and Nuclear Chemistry Letters 145, 143–149 (1990). https://doi.org/10.1007/BF02172365

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  • DOI: https://doi.org/10.1007/BF02172365

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