Skip to main content
SpringerLink
Log in

Comparative discussion of NH +4 formation mechanisms on oxide surfaces and in acidic media

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

A comparative study of NH +4 formation on aluminosilicate surface and in an aqueous solution of hydrochloric acid has been carried out in the framework of the nonempirical method with a STO-3G basis. It is suggested that the compensation mechanisms of energy consumptions to form protonated species in both cases are similar.

Abstract

В рамках неэмпирического метода в базисе СТО-3Г про-ведено сравнительное исследование реакций образования NH +4 на поверхности алюмосиликата и в водном ра-створе соляной кислоты. Делается вывод о сходстве механизмов компенсации энергетических эатрат на об-разование протонированной формы на поверхности и в кислой среде.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V.B. Kazanskii: Proc. 1st All-Union Conference Catalysis and Catalytic Processes in Production of Chemico-Pharmaceutical Compounds (Abstracts), p. 3 Moskva, All-Union Chemico-Technological Research Institute of Medical Industry, 1985.

    Google Scholar 

  2. A.G. Pelmenshchikov, V.I. Pavlov, G.M. Zhidomirov, Phys. Status Solidi B,130, 1 (1985).

    Google Scholar 

  3. E.A. Paukshtis, E.N. Yurchenko: Usp. Khim.,52, 426 (1983).

    Google Scholar 

  4. G.V. Tsitsishvili, D.V. Khuroshvili, G.M. Zhidomirov, A.G. Pelmenshchikov: React. Kinet. Catal. Lett.,25, 83 (1984).

    Article  Google Scholar 

  5. L. Little: Infrared Spectra of Adsorbed Molecules. Mir, Moskva 1969.

    Google Scholar 

  6. E. Clementi: J. Chem. Phys.,46, 385;47, 2323 (1967).

    Article  Google Scholar 

  7. Yu.D. Pankratiev, E.A. Paukshtis, V.M. Turkov, E.N. Yurchenko: Proc. Intern. Symposium on Zeolite Catalysis, p. 55, Siófok, Hungary 1985.

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    A. G. Pelmenshchikov, E. A. Paukshtis, N. U. Zhanpeisov, V. I. Pavlov & G. M. Zhidomirov

Authors
  1. A. G. Pelmenshchikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Paukshtis
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. U. Zhanpeisov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Pavlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. M. Zhidomirov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pelmenshchikov, A.G., Paukshtis, E.A., Zhanpeisov, N.U. et al. Comparative discussion of NH +4 formation mechanisms on oxide surfaces and in acidic media. React Kinet Catal Lett 33, 423–428 (1987). https://doi.org/10.1007/BF02128100

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02128100

Keywords

Search

Navigation