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Cluster quantum chemical study of the mechanism of selective oxidation of ethane to acetaldehyde on boron — Phosphorus mixed oxide catalysts

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Abstract

In the framework of semiempirical quantum chemical MINDO/3 method the selective oxidation of ethane to acetaldehyde on a specially modified boron — phosphorus mixed oxide catalyst has been considered. On the basis of the results of calculation a possible mechanism for this process is proposed.

Abstract

В рамках полуэмпирического квантовохимического метода MINDO/3 рассмотрено селективное окисление этана в ацетальдегид на специально модифицированном смешанном оксиде бора и фосфора. На основании полученных результатов расчетов предложен возможный механизм этого процесса.

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References

  1. K. Otsuka, Y. Uragami, M. Hatano: Catal. Today,13, 667 (1992).

    Google Scholar 

  2. K. Otsuka, Y. Uragami, T. Komatsu, M. Hatano: in: “Natural Gas Conversion”. Ed. A. Holmen, K-J. Jens, S. Kolboe, p. 15. Elsevier Amsterdam 1991.

    Google Scholar 

  3. Y. Murakami, K. Otsuka, Y. Wada, A. Morikawa: Bull. Chim. Soc. Japan,63, 340 (1990).

    Google Scholar 

  4. R.C. Bingham, M.J.S. Dewar, D.H. Lo: J. Am. Chem. Soc.,97, 1285 (1975).

    Google Scholar 

  5. G.M. Zhidomirov, A.G. Pelmenschikov, N.U. Zhanpeisov, A.G. Grebenyuk: Kinet. Katal.,28, 86 (1987).

    Google Scholar 

  6. G.M. Zhidomirov, N.U. Zhanpeisov: Catal. Today,13, 517 (1992).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, Russia

    N. U. Zhanpeisov

  2. Tokyo Institute of Technology, 152, Tokyo, Japan

    K. Otsuka

Authors
  1. N. U. Zhanpeisov
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  2. K. Otsuka
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Zhanpeisov, N.U., Otsuka, K. Cluster quantum chemical study of the mechanism of selective oxidation of ethane to acetaldehyde on boron — Phosphorus mixed oxide catalysts. React Kinet Catal Lett 48, 301–308 (1992). https://doi.org/10.1007/BF02070100

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  • DOI: https://doi.org/10.1007/BF02070100

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