Summary
Reaction of Lawessons reagent (MeOC6H4P(S)S2P(S)C6H4OMe) (1) withbis-phosphine-dihalide complexes of nickel, palladium and platinum proceeds with asymmetric bridge cleavage to give M(PR3)2(S2(S)PC6H4OMe) (2). The new compounds were characterised by31P n.m.r., i.r. and microanalyses.
Similar content being viewed by others
References
D. Klaman (Ed),Lubricants and Related Products, Verlag Chemie, Weinheim, F. R. G. (1984).
P. G. Harrison, M. J. Begley, T., Kikabhai and F. KillerJ. Chem. Soc., Dalton Trans., 925 (1986) and refs, therein.
J. R. Wasson, G. M. Waltermann and A. J. Stoklosa,Topics Current Chem.,35, 65 (1973).
W. Kuchen and H. Hertel,Angew. Chem. Int. Ed. Engl.,8, 89 (1969).
G. A. Zank and T. B. Rauchfuss,Organometallics,3, 1191 (1984).
R. Jones, D. J. Williams, P. T. Wood and J. D. Woollins,Polyhedron,6, 539 (1987).
R. A. Cherkasov, G. A. Kutrev and N. Pudovik,Tetrahedron,14, 2567 (1985).
V. Mark, C. H. Dungan, M. M. Crutchfield and J. R. Van Waser,Topics in Phosphorus Chemistry, Vol 5, Interscience, New York 1967.
J. P. Fackler, Jr., L. D. Thompson, I. J. B. Lin, T. A. Stephenson, R. O. Gould, J. M. C. Alison and A. J. Fraser,Inorg. Chem.,21, 2397 (1982)
R. Jones, C. P. Warrens, D. J. Williams and J. D. Woollins,J. Chem. Soc., Dalton Trans., 907 (1987).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wood, P.T., Woollins, J.D. The preparation of M(PR3)2 (S2(S)PC6H4OMe) (M=Ni, Pd, Pt) from Lawessons reagent. Transition Met Chem 12, 403–405 (1987). https://doi.org/10.1007/BF01171647
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01171647