Summary
Two new complexes derived from bis-N-(p-methoxyphenyl)-2, 5-furylideneimine(L) (1) and copper(II)[CuL2](ClO4)2·4H2O (2) and [(CuCl2)2L] (3), have been synthesized. The i.r. spectra of both complexes show that the ligand coordinatesvia oxygen and nitrogen. Spectral and magnetic properties are consistent with the formulation of (2) as an elongated tetragonal octahedral copper(II) structure and (3) as distorted square-planar copper(II) structure, where each copper atom is bonded to two chlorine, one oxygen and one nitrogen atoms, and two carbon and two copper atoms tetrahedrally surround the oxygen atom.
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Alvarez-Valdés, A., Camazón, M.J., Navarro-Ranninger, C. et al. New complexes derived from copper(II) salts and bis-N-(p-methoxyphenyl)-2, 5-furylideneimine. Transition Met Chem 12, 543–546 (1987). https://doi.org/10.1007/BF01023845
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DOI: https://doi.org/10.1007/BF01023845