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Redox properties of thiolate-bridged binuclear nickel(II) complexes and correlation of their electronic spectra

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Summary

The redox properties of a series of thiolate-bridged binuclear nickel(II) complexes with NNS-tridentate and SNNS-tetradentate thiolic ligands have been studied by cyclic voltammetry. The first redox potential (E1/2=−0.63 to −0.95 Vversus Ag/AgCl) has a linear correlation with the absorption maxima of the\(\tilde v_{d - d}\) transition.

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Authors and Affiliations

  1. Department of Chemistry School of Science, Kwansei Gakuin University, Uegahara, Nishinomiya 662, Japan

    Masahiro Mikuriya & Shinji Shigematsu

  2. Department of Chemistry, Faculty of Science, Shimane University, Matsue 690, Japan

    Makoto Handa

  3. Institute of Chemistry, College of General Education, Osaka University, Toyonaka, Osaka 560, Japan

    Takamitsu Kohzuma

Authors
  1. Masahiro Mikuriya
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  2. Shinji Shigematsu
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  3. Makoto Handa
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  4. Takamitsu Kohzuma
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Mikuriya, M., Shigematsu, S., Handa, M. et al. Redox properties of thiolate-bridged binuclear nickel(II) complexes and correlation of their electronic spectra. Transition Met Chem 16, 532–534 (1991). https://doi.org/10.1007/BF01024325

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  • DOI: https://doi.org/10.1007/BF01024325

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