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Cp*MCpMoFe(CO)7(μ3-S), Cp*MoCpMFe(CO)7(μ3-S) (M = W, Mo) and Cp*WCp*MoFe(CO)7(μ3-S). Crystal structure of CpMoCp*WFe(CO)7(μ3-S)

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Abstract

CpMoFeCo(CO)7(μ3-S) reacts with Cp*M(CO)3Cl or CpM(CO)3Cl (M = W, Mo) to gave the mixed-metal clusters Cp*WCpMoFe(CO)7(μ3-S) (1), Cp*MoCpMoFe(CO)7(μ3-S) (2), CpWCp*MoFe(CO)7(μ3-S) (3), CpMoCp*MoFe(CO)7(μ3-S) (4) and Cp*WCp*MoFe(CO)7(μ3-S) (5). The title clusters have been characterized by i.r., 1H/13C-n.m.r. spectroscopy and their compositions have been confirmed by elemental analyses. The X-ray crystal structure analysis shows the two independent enantiomeric molecules of clusters (1) in one crystal structure unit.

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Authors and Affiliations

  1. Institute of Photographic Chemistry, Chinese Academy of Sciences, Beijing, 100101, P.R. China

    Feng Xu & Yong-Mei Chen

  2. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences, Lanzhou, 730000, P.R. China

    Shi-Yan Yang

  3. Chengdu Centre of Analysis and Measurement, Chinese Academy of Sciences, Chengdu, 610041, P.R. China

    Wen-Hua Sun & Kai-Bei Yu

Authors
  1. Feng Xu
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  2. Yong-Mei Chen
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  3. Shi-Yan Yang
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  4. Wen-Hua Sun
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Xu, F., Chen, YM., Yang, SY. et al. Cp*MCpMoFe(CO)7(μ3-S), Cp*MoCpMFe(CO)7(μ3-S) (M = W, Mo) and Cp*WCp*MoFe(CO)7(μ3-S). Crystal structure of CpMoCp*WFe(CO)7(μ3-S). Transition Metal Chemistry 25, 108–111 (2000). https://doi.org/10.1023/A:1007072901162

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