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Copper(II) oxalate and oxamate complexes

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Abstract

Reaction of CuII salts with phenanthroline and oxalate (ox) or oxamate (oxm) gives [Cu(phen)(ox)(H2O)] · H2O or [Cu(phen)(oxm)(H2O)] · H2O complexes while direct treatment of CuII salts with oxalate or oxamate gives [NH4]2[Cu(ox)2] and [Cu(oxm)2(H2O)2] respectively. The X-ray structures of one example of each system, aquo-oxamato-phenanthroline-copper(II)-dihydrate and the polymeric ammonium-bis(aquo)-tetraoxalato-dicopper(II)-dihydrate, are reported.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Masaryk University, Kotlařskă 2, 611 37, Brno, Czech Republic

    Josef Novosad

  2. Department of Chemistry, University of Ioannina, Ioannina, Greece

    Argyro C. Messimeri, Christos D. Papadimitriou & Panos G. Veltsistas

  3. School of Chemistry, University of St. Andrews, St. Andrews, Fife, KY16 9ST, Scotland

    J. Derek Woollins

Authors
  1. Josef Novosad
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  2. Argyro C. Messimeri
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  3. Christos D. Papadimitriou
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  4. Panos G. Veltsistas
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  5. J. Derek Woollins
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Novosad, J., Messimeri, A.C., Papadimitriou, C.D. et al. Copper(II) oxalate and oxamate complexes. Transition Metal Chemistry 25, 664–669 (2000). https://doi.org/10.1023/A:1007068914946

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