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Thiocarbonyl rhodium complexes with tricyclohexylphosphine and other nitrogen and phosphorus donor ligands

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Summary

The preparation of the covalent Rh(OCIO3)(CS)(PCy3)2 and Rh(OClO3)(CS)(PPh3)(PCy3) perchlorato complexes is described, These complexes react with mono- or bidentate nitrogen donor ligands to give new cationic complexes of the [Rh(CS)(PCY3)2L]ClO4 and [Rh(CS)(PPh,)(PCy3)L]ClO4 types,

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Authors and Affiliations

  1. Department of Inorganic Chemistry, University of Zaragoza, Zaragoza, Spain

    Rafael Usón, Pascual Lahuerta, Daniel Carmona & Luis A. Oro

Authors
  1. Rafael Usón
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  2. Pascual Lahuerta
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  3. Daniel Carmona
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  4. Luis A. Oro
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Usón, R., Lahuerta, P., Carmona, D. et al. Thiocarbonyl rhodium complexes with tricyclohexylphosphine and other nitrogen and phosphorus donor ligands. Transition Met Chem 5, 327–329 (1980). https://doi.org/10.1007/BF01396952

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  • DOI: https://doi.org/10.1007/BF01396952

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