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The synthesis and structure of bis(acetonitrile)nitrosyl tris(3,5-dimethylpyrazolyl)borato molybdenum hexafluorophosphate

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Summary

Treatment of [Mo{HB(3,5-Me2C3HN2)3}(NO)I2] with one or two moles of AgPF6 in acetonitrile afforded the paramagnetic (one unpaired electron) complex [Mo{HB(3,5-Me2C3NH2)3}(NO)(NCMe)2][PF6]. The structure of this complex was determined crystallographically, and the six-coordinate geometry of the complex cation confirmed.

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Authors and Affiliations

  1. Department of Chemistry, University of Birmingham, P.O. Box 363, B15 2TT, Birmingham, UK

    Gianfranco Denti, Mauro Ghedini & Jon A. McCleverty

  2. Department of Chemistry, University of Sheffield, S3 7HF, Sheffield, UK

    Harry Adams & Neil A. Bailey

Authors
  1. Gianfranco Denti
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  2. Mauro Ghedini
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  3. Jon A. McCleverty
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  4. Harry Adams
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  5. Neil A. Bailey
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Denti, G., Ghedini, M., McCleverty, J.A. et al. The synthesis and structure of bis(acetonitrile)nitrosyl tris(3,5-dimethylpyrazolyl)borato molybdenum hexafluorophosphate. Transition Met Chem 7, 222–224 (1982). https://doi.org/10.1007/BF00618012

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  • DOI: https://doi.org/10.1007/BF00618012

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