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Synthesis and structure of a mono-chloro bridged copper(II) dimer containing a linear CuII-Cl-CuII bridge

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References

  1. K. D. Karlin, J. C. Hayes, Y. Gultneh, R. W. Cruse, J. W. McKown, J. P. Hutchinson and J. Zubieta,J. Am. Chem. Soc.,106, 2121 (1984).

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  2. K. D. Karlin, Y. Gultneh, J. C. Hayes and J. Zubieta,Inorg. Chem., 23, 519 (1984).

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  3. K. D. Karlin, P. L. Dahlstrom, L. T. DiPierro, R. A. Simon and J. Zubieta,J. Coord. Chem., 11, 61 (1981).

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  4. K. D. Karlin, J. C. Hayes and J. Zubieta in K. D. Karlin and J. Zubieta (Eds.),Copper Coordination Chemistry: Biochemical and Inorganic Perspectives, Adenine Press: Guilderland, New York, 1983, pp. 457–472.

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  5. K. D. Karlin, Y. Gultneh, J. P. Hutchinson and J. Zubieta,J. Am. Chem. Soc., 104, 5340 (1982).

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  6. J. Zubieta, K. D. Karlin and J. C. Hayes in reference 4, pp. 97–108.

  7. K. D. Karlin, J. C. Hayes, S. Juen, J. P. Hutchinson and J. Zubieta,Inorg. Chem., 21, 4106 (1982).

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  8. When Et2O is added to this initial solution, a light blue precipitate is obtained. It is recrystallized from MeOH-ether to obtain a blue crystalline material formulated as the neutral monomeric complex Cu(py2)Cl2. (Found: C, 46.6; H, 4.7; N, 11.7; CuC14H17N3Cl2 calcd. C, 46.8; H, 4.8; N, 11.6%.)

  9. Found: C, 40.5; H, 4.1; N, 10.2; Cu2C28H34N6Cl3(PF6) calcd.: C, 40.7; H, 4.1; N, 10.1%.

  10. For other examples of mono-chloro bridged CuII dimers, see: R. A. Bauer, W. R. Robinson and D. W. Marqerum,J. Chem. Soc., Chem. Comm., 289 (1973); H. Gampp, M. M. Roberts and S. J. Lippard, to be submitted.

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Authors and Affiliations

  1. Department of Chemistry, State University of New York (SUNY) at Albany, 12222, Albany, New York

    Kenneth D. Karlin, Jeffrey W. McKown, Jon C. Hayes, John P. Hutchinson & Jon Zubieta

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  1. Kenneth D. Karlin
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  2. Jeffrey W. McKown
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  3. Jon C. Hayes
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  4. John P. Hutchinson
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  5. Jon Zubieta
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Karlin, K.D., McKown, J.W., Hayes, J.C. et al. Synthesis and structure of a mono-chloro bridged copper(II) dimer containing a linear CuII-Cl-CuII bridge. Transition Met Chem 9, 405–406 (1984). https://doi.org/10.1007/BF00637031

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