Abstract
The infrared chemiluminescence technique has been applied to the catalytic oxidation of CO on a Pt(110)(1×2) surface. The vibrational and the rotational states of CO2 formed on the reconstructed Pt(110)(1×2) surface are more excited than those on the terrace Pt(111) surface. The vibrational state of the product CO2 strongly depends on the CO coverage: the vibrational temperature (TV) of the product CO2 becomes higher, as the coverage of CO increases.
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Watanabe, K., Uetsuka, H., Ohnuma, H. et al. The dynamics of CO oxidation on Pt(110) studied by infrared chemiluminescence of the product CO2: effect of CO coverage. Catalysis Letters 47, 17–20 (1997). https://doi.org/10.1023/A:1019072030382
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DOI: https://doi.org/10.1023/A:1019072030382