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Diethoxysilane formation by the disproportionation of triethoxysilane over heat-treated calcium hydroxide

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Abstract

The disproportionation of triethoxysilane was carried out in a fixed-bed flow reactor over the solids obtained by heat-treating calcium hydroxide at various temperatures. In the disproportionation, the reaction proceeding to completeness to afford silane and tetraethoxysilane occurs to far lesser extent: predominantly diethoxysilane is obtained together with tetraethoxysilane. Dimethoxysilane is obtained by the disproportionation of trimethoxysilane also over the heat- treated calcium hydroxide.

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Authors
  1. E. Suzuki
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  2. Y. Nomoto
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  3. M. Okamoto
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  4. Y. Ono
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Suzuki, E., Nomoto, Y., Okamoto, M. et al. Diethoxysilane formation by the disproportionation of triethoxysilane over heat-treated calcium hydroxide. Catalysis Letters 48, 75–78 (1997). https://doi.org/10.1023/A:1019050314878

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  • DOI: https://doi.org/10.1023/A:1019050314878

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