Skip to main content
SpringerLink
Log in

SnO2‐supported palladium catalysts: activity in deNOx at low temperature

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

High surface area tin dioxide (174 m2/g) has been synthetised and characterised by XRD, TEM and UV‐visible DRS. DRS gives evidence for the formation of oxygen vacancies (donor levels) under reducing conditions. CO adsorption gives rise to terminal carbonyl species linked to Sn4+ and Sn2+. Palladium–tin oxide catalysts have been prepared from various precursors (Pd(acac)2 and Pd(NO3)2) and by different preparation methods (grafting, photodeposition); they are active in deNOx reactions at low temperature (180 °C) in the presence of stoichiometric CO–NO–O2 mixtures. A mechanism involving palladium and oxygen vacancies is proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J.F. Aller, T. Moseley, J.O. Norris and D.E. Williams, J. Chem. Soc. Faraday Trans. I 83 (1987) 1323

    Article  Google Scholar 

  2. G. Heiland, Sensors Actuators 2 (1982) 343.

    Article  CAS  Google Scholar 

  3. M. Sheintuch, J. Schmidt, Y. Lechtman and G. Yahav, Appl. Catal. 49 (1989) 55.

    Article  CAS  Google Scholar 

  4. J.-M. Herrmann, J. Disdier, P. Pichat, A. Fernandez, A. Gonzalez-Elipe, G. Munuera and C. Leclercq, J. Catal. 132 (1991) 490.

    Article  CAS  Google Scholar 

  5. A. Trovarelli, Catal. Rev. 38 (1996) 439

    CAS  Google Scholar 

  6. S. Bernal, J.J. Calvino, M.A. Cauqui, J.M. Gatica, C. Larese, J.A. Perez Omil and J.M. Pintado, Catal. Today 50 (1999) 175

    Article  CAS  Google Scholar 

  7. J. Kaspar, P. Fornasiero and M. Graziani, Catal. Today 50 (1999) 285.

    Article  CAS  Google Scholar 

  8. M.M. Gadgil, R. Sasikala and S.K. Kulshreshtha, J. Mol. Catal. 87 (1994) 297

    Article  CAS  Google Scholar 

  9. Y. Teraoka, T. Harada, T. Iwasaki, T. Ikeda and S. Kagawa, Chem. Lett. (1993) 773

  10. M.J. Fuller and M.E. Warwick, Chem. Ind. (1976) 787.

  11. S.P. Tandon and J.P. Gupta, Phys. Stat. Sol. 38 (1970) 363.

    CAS  Google Scholar 

  12. G. Ghiotti, A. Chiorino, G. Martinelli and M.C. Carotta, Sensors Actuators B 24/25 (1995) 520.

    Article  Google Scholar 

  13. P.A. Cox, Transition Metal Oxides (Clarendon Press, Oxford, 1992).

    Google Scholar 

  14. D. Tessier, A. Rakaï and F. Bozon-Verduraz, J. Chem. Soc. Faraday Trans. 88 (1992) 741.

    Article  CAS  Google Scholar 

  15. J. Benson and M. Boudart, J. Catal. 4 (1964) 704.

    Article  Google Scholar 

  16. Y.A. Lokhov and A. Davydov, Kinet. Katal. 21 (1980) 1515, 1523.

    CAS  Google Scholar 

  17. C. Naccache, M. Primet and M. Mathieu, Adv. Chem. Ser. 121 (1973) 266.

    Article  CAS  Google Scholar 

  18. A. Badri, C. Binet and J.C. Lavalley, J. Phys. Chem. 86 (1989) 451.

    Google Scholar 

  19. D. Amalric, F. Bozon-Verduraz and D. Fatu, in: 4th European Congress on Catalysis, Rimini, 1999

  20. D. Amalric, J.-M. Herrmann, A. Ensuque and F. Bozon-Verduraz, to be published.

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux Divisés et Catalyse, Université Paris 7‐Denis Diderot, 2, place Jussieu, 75251, Paris Cedex 05, France

    D. Amalric‐Popescu & F. Bozon‐Verduraz

Authors
  1. D. Amalric‐Popescu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. Bozon‐Verduraz
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Amalric‐Popescu, D., Bozon‐Verduraz, F. SnO2‐supported palladium catalysts: activity in deNOx at low temperature. Catalysis Letters 64, 125–128 (2000). https://doi.org/10.1023/A:1019051407087

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1019051407087

Search

Navigation