Abstract
The main features of the pulse transient method are presented. The method gives the specific heat c and thermal diffusivity a for a single measurement, while thermal conductivity λ is calculated according to λ=caρ, where ρ is the density. The pulse transient method is a dynamic method based on the measurement of the temperature response to a heat pulse produced within a specimen. An apparatus operating in the temperature range from −40 to 100°C is described. Errors are discussed. The thermophysical properties of a CsPbCl3 single crystal are determined using the pulse transient method for a temperature range between 10 and 65°C in the controlled heating and cooling regimes. The data show anomalies in the thermophysical properties around the phase transition temperature at 47°C. Discrepancies in comparison with previously published data are discussed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
L' KubiCáar, Pulse method of measuring basic thermophysical parameters, in Wilson H Wilson's Comprehensive Analytical Chemistry, Vol. XII, Thermal Analysis, Part E, G. Svehla, ed. (Elsevier, Amsterdam, 1988), pp. 1–350.
L' Kubicarcánd V. Bohác, in Proc. 25th Int. Thermal Conductivity Conf. 12th Int. Thermal Dilatation Symp., Pittsburgh, October 26–29, 1997, P. S. Gaal, ed. (Technomic, Basel, 1999), p. 135.
P. Anderson and G. Báckstrom, Rev. Sci. Instrum. 47:205 (1976).
S.E. Gustaffson, Rev. Sci. Instrum. 62:797 (1991).
L'Kubicár, High Temp. High Press. 17:497 (1985).
J. Spišiak, L'. Kubicár, and D. Křivanková, Int. J. Thermophys. 12:593 (1991).
J.Šestak, Thermophysical properties of solids, their measurements and theoretical thermal analysis, in Wilson H Wilson's Comprehensive Analytical Chemistry, Vol. XII, Thermal Analysis, Part D, G. Svehla, ed. (Elsevier, Amsterdam, 1988), pp. 1–619.
M.J. Richardson, in Compendium of Thermophysical Property Measurement, Vol. 2, Recommended Measurement Techniques and Practices, K. D. Maglic, A. Cezairliyan, and V. E. Peletsky, eds. (Plenum, New York, 1992), pp. 519–545.
E.D. West and E. F. Westrum, Jr., in Experimental Thermodynamics, Vol. 1, J. P. McCullough and D. W. Scott, eds. (Butterworths, London, 1968), pp. 333–365.
B. Douglass and E. G. King, in Experimental Thermodynamics, Vol. 1, J. P. McCullough and Donald W. Scott, eds. (Butterworths, London, 1968), pp. 293–330.
K. D. Maglic and R. E. Taylor, in Compendium of Thermophysical Property Measurement Methods, Vol. 1, Recommended Measurement Techniques and Practices, K. D. Maglic , A. Cezairliyan, and V. E. Peletsky, eds. (Plenum, New York, 1992), pp. 281–314.
M. J. Laubnitz, in Compendium of Thermophysical Property Measurement Methods, Vol. 1, Survey of Measurement Techniques, K. D. Maglic , A. Cezairliyan, and V. E. Peletsky, eds. (Plenum, New York, 1984), pp. 11–59.
N. A. Torberg-Jensen, J. Chem. Phys. 50:559 (1969).
T. Sakudo, H. Unoki, Y. Fujii, J. Kobayashi, and M. Yamada, Phys. Lett. A 28:542 (1969).
S. Hirotsu and T. Suzuki, J. Phys. Soc. Jap. 44:1604 (1978).
K. Nitsch, A. Cihlar , Z. Malkova , M. Rodová, and M. Vaneček, J. Cryst. Growth. 131:612 (1993).
S. Hirotsu, J. Phys. Soc. Jap. 31:552 (1971).
I. N. Flerov and K. S. Aleksandrov, Fiz. Tverd. Tela 16:1509 (1974) [in Russian].
Y. Fuji, S. Hashino, Y. Yamada, and G. Shirane, Phys. Rev. B 9:4549 (1974).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kubičár, L., Boháč, V. & Nitsch, K. Thermophysical Properties of the CsPbCl3 Single Crystal Using Pulse Transient Method1 . International Journal of Thermophysics 21, 571–583 (2000). https://doi.org/10.1023/A:1006668520775
Issue Date:
DOI: https://doi.org/10.1023/A:1006668520775