Abstract
Results are reported of an experimental study of superheated rubidium vapor in the temperature range 1450–2000 K and pressure range 1.7–5.2 MPa and potassium in the range 1500–2100 K and 1.4–4.0 MPa. The experiments have been performed with an apparatus adaoted to implement a modified constant-volume piezometer technique, where the sensing element of a pressure transducer represented by a diaphragm is placed in a low-temperature zone. A dosing device is described which permits the performance of accurate measurements of the mass of the metal in the piezometer chamber. The present results are in good agreement with those reported by other investigators in the overlaping temperature and pressure ranges.
Similar content being viewed by others
References
F. Teppor, A. Murchison, J. Zelenak, and F. Roehlich, Thermophysical Properties of Rubidium and Cesium, Report MSAR-63-116 (Mine Safety Appliances Research Corp., Callery, Pa., 1963), p. 42.
P. Y. Achener, Thermodynamic and Transport Properties of Cesium and Rubidium, PVT Properties, AGN Report No. 8192, Vol. 1 (San Ramon, Calif., 1967), p. 112.
J. P. Stone, C. T. Ewing, J. R. Span, E. W. Steinkuller, D. C. Williams, and R. R. Miller, J. Chem. Eng. Data 11:309 (1966).
L. V. Gurvich, I. V. Vents, and V. A. Medvedev, et al., Termodinamicheskie Svoistva Individualnykh Veschestv (Thermodynamic Properties of Individual Substances), Handbook, 3rd ed., Vol. IV, Book 1 (M. Nauka, 1982), pp. 512–516.
T. D. Reva and A. M. Semenov, Teplofiz. Vysok. Temp. 22:463, 692, 874 (1984).
L. D. Voljak, V. G. Stepanov, and V. D. Scherbakov, Thermodynamic Properties of Gaseous Cesium at High Temperatures and Pressures, Proceedings of the Eight Symposium on Thermophysical Properties, Vol. 2, J. V. Sengers, ed. (ASME, New York, 1982), pp. 176–178.
N. B. Vargaftik, L. D. Voljak, and V. G. Stepanov, et al., Teplofiz. Vysok. Temp. 23:692 (1985).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Voljak, L.D., Nikitin, A.N. & Stepanov, V.G. Experimental research on specific volumes of rubidium and potassium vapors. Int J Thermophys 8, 239–246 (1987). https://doi.org/10.1007/BF00515206
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00515206