Abstract
Solid-liquid phase equilibria of the benzene + 2-methyl-2-propanol system have been investigated at temperatures from 278 to 323 K and pressures up to 300 MPa using a high-pressure optical vessel. The uncertainties of the measurements of temperature, pressure and composition are within ±0.1 K, ±0.5 MPa, and ±0.001 mole fraction, respectively. The freezing pressure at a constant composition increases monotonously with pressure. The eutectic point shifts to a higher temperature and benzene-rich composition with increasing pressure. In order to describe the pressure-temperature-composition relation of high-pressure solid-liquid phase equilibria, a new simple equation has been proposed as follows:
where B, C, and D are the temperature-dependent coefficients and are expressed by the polynomials of reciprocal of temperature. It is found that the solid-liquid coexistence curves of both eutectic systems and solid-solution systems can be correlated satisfactorily by this equation.
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Nagaoka, K., Makita, T. Solid-liquid phase equilibria of benzene + 2-methyl-2-propanol system under high pressures. Int J Thermophys 9, 61–71 (1988). https://doi.org/10.1007/BF00504000
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DOI: https://doi.org/10.1007/BF00504000