Abstract
The synthesis and crystal and molecular structure of the title compound is reported. It belongs to the monoclinic space groupP21/a witha=29.3990 (20),b=7.1150 (6),c=8.3140 (9) Å,β=98.060 (9)° andZ=4. The structure was refined to a finalR of 3.52% (R w %=3.82) for 2354 observed reflections. Vibrational spectra have been recorded and discussed.
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References
Adams, M. J. Hodgkin, D. C., and Raeburn, U. A. (1970)J. Chem. Soc. A, 2632–2635.
Alshaikh-Kadir, K., Drew, M. G. B., and Holt, P. (1978)Acta Cryst. B 34, 939–941.
Authier-Martin, M., and Beauchamp, A. L. (1977)Can. J. Chem. 55, 1213–1217.
Benedetti, A. Preti, C., and Tosi, G. (1984a)J. Mol. Struct. 116, 397–409 and references therein quoted.
Benedetti, A. Preti, C., and Tosi, G. (1984b) XXIII International Conference on Coordination Chemistry, Boulder, Colorado (U.S.A.), July 29–August 3, Abstracts of Papers, p. 364.
Biscarini, P., and Nivellini, G. D. (1969)J. Chem. Soc. A, 2206–2210.
Camerman, A., and Camerman, N. (1972)J. Am. Chem. Soc. 94, 268–272.
Canty, A. J., and Deacon, G. B. (1980)Inorg. Chim. Acta 45, L225-L227.
Cinellu, M. A., Ganadu, M. L., Minghetti, G., Cariati, F., Demartin, F., and Manassero, M. (1984) XVII Congresso Nazionale di Chimica Inorganica, Cefalù (Italy), October 15–19, Abstracts of Papers, p. 489.
Cromer, D. T., and Waber, J. T. (1974)International Tables for X-ray Crystallography, Vol. IV, J. A. Ibers and W. C. Hamilton, eds. (Kynoch Press, Birmingham, England), pp. 99–101, 149–150.
Dean, P. A. W. (1978)Prog. Inorg. Chem. 24, 109–178.
Galdecki, Z., and Glowka, M. L. (1980)Acta Cryst. B 36, 3044–3048.
Genet, F., and Leguen, J. C. (1969)Acta Cryst. B 25, 2029–2033.
Gilli, G., Bertolasi, V., Sacerdoti, M., and Borea, P. A. (1977)Acta Cryst. B 33, 2664–2667.
Gilli, G., Bertolasi, V., Sacerdoti, M., and Borea, P. A. (1978)Acta Cryst. B 34, 2826–2829.
Grdenic, D. (1965)Q. Rev. 19, 303–328.
Johnson, C. K. (1965)Ortep, Report ORNL-3794, Oak Ridge National Laboratory, Oak Ridge, Tennessee.
Majeste, R. J., and Trefonas, L. M. (1972)Inorg. Chem. 11, 1834–1836.
McPhail, A. T., and Sim, G. A. (1966)J. Chem. Soc. Chem. Commun., 21–22.
Minghetti, G., Ganadu, M. L., Foddai, C., Cinellu, M. A., Cariati, F., Demartin, F., and Manassero, M. (1984)Inorg. Chim. Acta 86, 93–100.
Miyamae, H., Obata, A., and Kawazura, H. (1982)Acta Cryst. B 38, 272–274.
Mosset, A., Tuchagues, J. P., Bonnet, J. J., Haran, R., and Sharrock, P. (1980)Inorg. Chem. 19, 290–294.
North, A. C. T., Phillips, D. C., and Mathews, F. S. (1968)Acta Cryst. A 24, 351.
Sheldrick, G. M. (1976)Shelx-76, Program for Crystal Structure Determination (University Chemical Laboratory, Cambridge, England).
Taylor, N. J., Wong, Y. S., Chieh, P. C., and Carty, A. J. (1975)J. Chem. Soc. Dalton Trans., 438–442.
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Antolini, L., Preti, C., Tosi, G. et al. Structural and spectral study of 7-chloro-3-hydroxy-1-methyl-5-phenyl-1,3-dihydro-2H-1,4-benzodiazepin-2-one (temazepam)mercury(II) dichloride. Journal of Crystallographic and Spectroscopic Research 16, 115–124 (1986). https://doi.org/10.1007/BF01566052
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DOI: https://doi.org/10.1007/BF01566052