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The crystal and molecular structure of N-(methylsulfonyl)-N-(2,6)-(dimethylphenyl)methanesulfonamide

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Abstract

The title compound, crystallizes in the triclinic space group\(P\bar 1\) witha=8.232(4),b=9.159(2),c=10.230(3)Å. α=74.07(3)°, β=72.50(4)°, γ=63.65(3)° andZ=2. The structure was solved by direct methods and refined by full matrix least squares methods toR=0.054 for 1817 observed reflections. The plane containing the nitrogen and sulfur atoms is perpendicular to the aromatic plane. One of the S−O bonds in each methanesulfonyl group is in nearly eclipsed conformation with the N−C bond.

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Authors and Affiliations

  1. Department of Chemistry, King Fahd University of Petroleum and Minerals, 31261, Dhahran, Saudi Arabia

    Mazhar-Ul-Haque & Sk. Asrof Ali

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  1. Mazhar-Ul-Haque
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  2. Sk. Asrof Ali
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Mazhar-Ul-Haque, Ali, S.A. The crystal and molecular structure of N-(methylsulfonyl)-N-(2,6)-(dimethylphenyl)methanesulfonamide. J Chem Crystallogr 24, 759–762 (1994). https://doi.org/10.1007/BF01666966

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  • DOI: https://doi.org/10.1007/BF01666966

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