Abstract
The X-ray crystal structure of tetramethyl thiophenetetracarboxylate has been determined. Colourless, plates of C12H12O8S crystallise in the orthorhombic space group Pbca with cell dimensionsa=18.321(7),b=17.98(1),c=8.675(6)Å;V=2858(5)Å3 andz=8.1568 unique reflections withI net>2σ(I) on refinement afforded values ofR=0.040 andR w=0.034.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Michael, A.Chem. Ber. 1985,28, 1635.
Franz, J.E.; Black, L.L.Tetrahedron Lett. 1970, 1381–1384.
Bridson, J.N.; Copp, S.B.; Schriver, M.J.; Zhu, S.; Zaworotko, M.J.Can. J. Chem. 1994,72, 1143–1153.
TEXSAN-TEXRAY, Structure Analysis Package, Molecular Structure Corporation, 1985.
Cromer, D.T.; Waber, J.T.International Tables for X-Ray Crystallograph, Vol IV; The Kynoch Press: Birmingham, 1974, Table 2.2A.
Johnson, C.K.ORTEPII. Report ORNL-5138; Oak Ridge National Laboratory; Tenn., 1976.
Bak, B.; Christensen, D.; Hansen-Nygaard, L.; Rastrup-Andersen, J.J. Mol. Spectrosc. 1961,7, 58–63.
Pauling, L.The Nature of the Chemical Bond, 3rd Ed.; Cornell University, Press: Ithaca, 1960.
March, J.Advanced Organic Chemistry, 3rd Ed.; Wiley: New York, 1985; p 19 and references therein.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bridson, J.N., Schriver, M.J. & Zhu, S. X-ray structure of tetramethyl thiophenetetracarboxylate. J Chem Crystallogr 24, 801–803 (1994). https://doi.org/10.1007/BF01668244
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01668244