Skip to main content
SpringerLink
Log in

Crystal structure of a macrocyclic tetraamine isocyanato zinc(II) complex

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The complex, [Zn(L)(NCO)]Cl · 3H2O (1) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,01.18,07.12]docosane), has been synthesized and structurally characterized. 1 crystallizes in the monoclinic system, space group P21/n with a = 10.530(3), b = 9.315(2), c = 27.188(3) Å, β = 92.58(1)°, V = 2664.1(9)Å3, and Z = 4. The zinc atom is in a distorted squarepyramidal environment with the four nitrogen atoms of the macrocycle and one nitrogen atom of the isocyanate ligand.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kimura, E.; Koike, T. Comments Inorg. Chem. 1991, 11, 285.

    Google Scholar 

  2. Shelton, V.; Morrow, J.R. Inorg. Chem. 1991, 30, 4295.

    Google Scholar 

  3. Alsfasser, R.; Ruf, M.; Trafimenko, S.; Vahrenkamp, H. Chem. Ber. 1993, 126, 703.

    Google Scholar 

  4. Kimura, E.; Shiota, T.; Koike, T.; Shiro, M.; Kodama, M. J. Am. Chem. Soc. 1990, 112, 5805.

    Google Scholar 

  5. Gellman, S. H.; Petter, R.; Breslow, R. J. Am. Chem. Soc. 1986, 108, 8304.

    Google Scholar 

  6. Norman, P.R. Inorg. Chim. Acta 1987, 130, 1.

    Google Scholar 

  7. Woolley, P. Nature (London) 1975, 258, 677.

    Google Scholar 

  8. Silverman, D.N.; Lindskog, S. Acc. Chem. Res. 1988, 21, 30.

    Google Scholar 

  9. Kimura, E.; Koike, T.; Shionoya, M. Shiro, M. Chem. Lett. 1992, 780.

  10. Perrin, D.D.; Armarego, W.L.F.; Perrin, D.R. Purification of Laboratory Chemicals; 2nd Ed.; Pergamon Press: New York; 1985.

    Google Scholar 

  11. Kang, S.-G.; Kweon, J.K.; Jung, S.-K. Bull. Kor. Chem. Soc. 1991, 12, 483.

    Google Scholar 

  12. Choi, K. Y.; Suh, I.H.; Kim, J.C. Polyhedron 1997, 16, 1783.

    Google Scholar 

  13. Sheldrick, G.M. SHELXS90. Program for the Solution of Crystal Structures; University of Göttingen: Germany, 1990.

    Google Scholar 

  14. Sheldrick, G.M. SHELXL97. Program for the Refinement of Crystal Structures; University of Göttingen: Germany, 1997.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Mokwon University, Taejon, 301-729, Korea

    Ki-Young Choi & Kang Moon Chun

  2. Department of Physics, Chungnam National University, Taejon, 305,764, Korea

    Il-Hwan Suh

Authors
  1. Ki-Young Choi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kang Moon Chun
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Il-Hwan Suh
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Choi, KY., Chun, K.M. & Suh, IH. Crystal structure of a macrocyclic tetraamine isocyanato zinc(II) complex. Journal of Chemical Crystallography 28, 831–834 (1998). https://doi.org/10.1023/A:1021831921283

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1021831921283

Search

Navigation