Abstract
Two new mixed metal cluster complexes PtRu3(CO)10(PPh3)(μ3-S)2,3 14% yield and PtRu3(CO)9(PPh3)2(μ3-S)2,4 23% yield were obtained from the reaction of Ru3(CO)9(μ3-S)2,1 with Pt(PPh3)2(C2H4) at 0°C. The cluster of4 consists of a spiked triangle of four metal atoms with two triply bridging sulfido ligands. The reaction of Ru4(CO)11(μ4-S)2,2 with Pt(PPh3)2(C2H4) yielded the expanded mixed-metal cluster complex PtRu4(CO)12(PPh3)(μ4-S)2,5 in 12% yield. The structure of the cluster5 can be described as a pentagonal bipyramid of five metal atoms and two sulfido ligands with one metal-metal bond missing. Compounds4 and5 were characterized by a single-crystal X-ray diffraction analyses.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
R. D. Adams, inThe Chemistry of Metal Cluster Complexes, D. F. Shriver, H. D. Kaesz, and R. D. Adams (eds.) (VCH Publishers, New York, 1990, Chap. 3.
H. Vahrenkamp (1982).Phil. Trans. R. Soc. Lond. A308, 17.
H. Vahrenkamp (1975).Angew. Chem. Int. Ed. Engl. 14, 322.
L. E. Bogan, D. A. Lesch, and T. B. Rauchfuss (1983).J. Organomet. Chem. 250, 429.
V. Day, D. A. Lesch, and T. B. Rauchfuss (1982).J. Am. Chem. Soc. 104, 1290.
D. J. Darensbourg and D. J. Zalewski (1984).Organometallics 3, 1598.
R. D. Adams (1985).Polyhedron 4, 2003.
R. D. Adams and M. Tasi (1990).J. Cluster Sci. 1, 249.
R. D. Adams, I. T. Horvath, and S. Wang (1985).Inorg. Chem. 24, 1728.
R. D. Adams, I. T. Horvath, and L.-Y. Yang (1983).J. Am. Chem. Soc. 105, 1533.
R. D. Adams, D. F. Foust, and B. E. Segmüller (1983).J. Am. Chem. Soc. 105, 832.
R. D. Adams, I. T. Horvath, and P. Mathur (1984).J. Organomet. Chem. 262, 243.
R. D. Adams, I. T. Horvath, and P. Mathur (1984).Organometallics 3, 623.
R. D. Adams, J. E. Babin, and M. Tasi (1986).Inorg. Chem. 25, 4460.
R. D. Adams, J. E. Babin, and T. A. Wolfe (1989).Polyhedron 8, 1123.
R. D. Adams, I. T. Horvath, and P. Mathur (1984).J. Am. Chem. Soc. 106, 6296.
R. D. Adams, J. E. Babin, M. Tasi, and J.-G. Wang (1988).Organometallics 7, 755.
R. D. Adams, J. E. Babin, J.-G. Wang, and W. Wu (1989).Inorg. Chem. 28, 703.
R. D. Adams, J. E. Babin, and M. Tasi (1986).Inorg. Chem. 25, 4514.
R. D. Adams and T. S. A. Hor (1984).Inorg. Chem. 23, 4723.
R. D. Adams, T. S. A. Hor, and I. T. Horvath (1984).Inorg. Chem. 23, 4733.
R. D. Adams, J. E. Babin, and M. Tasi (1987).Inorg. Chem. 26, 2807.
U. Nagel (1982).Chem. Ber. 115, 1998.
B. F. G. Johnson, J. Lewis, P. G. Lodge, P. R. Raithby, K. Henrick, and M. J. McPartlin (1979).J. Chem. Soc., Chem. Commun. 719.
International Tables for X-ray Crystallography (Kynoch Press, Birmingham, England, 1975), Vol. IV; (a) Table 2.2B, pp. 99–101; (b) Table 2.3.1, pp. 149–150.
R. D. Adams, I. T. Horvath, B. E. Segmuller, and L.-Y. Yang (1983).Organometallics 2, 144.
R. Mathieu, M. Lenzi, and R. Poilblanc (1970).Inorg. Chem. 9, 2030.
E. J. Forbes, N. Goodhand, D. L. Jones, and T. A. Hamor (1979).J. Organomet. Chem. 182, 143.
R. D. Adams, I. T. Horvath, and S. Wang (1985).Inorg. Chem. 24, 1728.
R. D. Adams, J. E. Babin, L. Natarajan, M. Tasi, and J.-G. Wang (1987),Inorg. Chem. 26, 3708.
D. M. P. Mingos (1984).Acc. Chem. Res. 17, 311;
F. A. Cotton, inChemical Applications of Group Theory (John Wiley & Sons, New York, 1990), pp. 238–240.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Adams, R.D., Lii, JC. & Wu, W. Cluster synthesis. 42. The synthesis and crystal and molecular structures of the sulfur-bridged platinum-ruthenium carbonyl cluster compounds PtRu3(CO)9 L(PPh3)(μ3-S)2 (L=CO, PPh3) and PtRu4(CO)12(PPh3)(μ4-S)2 . J Clust Sci 4, 423–437 (1993). https://doi.org/10.1007/BF00703735
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00703735