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Transition metal 1,2-bidentate thiolates as building blocks and their construction into cluster complexes

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Abstract

Simple fragments of transition metal 1,2-bidentate thiolates, the so-called building blocks of the general compositions ML3, ML2, ML, M(O)L2, ML2L′, MLL′, etc. have been proposed to constitute the di-, tri- and tetranuclear complexes concerned in this review. Structureal regularities and characteristics have been discussed and summarized according to the thiolato ligands edt and pdt, bdt and tdt, mp, and mpo, and mpp, respectively.

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Abbreviations

H2mpo:

o-mercaptophenol

Hmpo:

2-mercaptopyridine-N-oxide

R2dtc:

N,N-dialkyldithiocarbamate

Haet:

2-aminoethanethiol

H2bdt:

o-benzenedithiol

H2pdt:

1,2-propanedithiol

H2tdt:

toluene-3,4-dithiol

Hmpp-mppH:

bis-(3-hydroxy-2-pyridyl)disulfide

Hmp-mpH:

bis-(2-oxyphenyl)disulfide

H2edt:

1,2-ethanedithiol

dppe:

1,2-bis(diphenylphosphino)ethane

H2tedt:

3,4,5,6-tetrachlorobenzene-1,2-dithiol

H2tpdt:

3-thiapentane-1,5-dithiol

H2mnt:

maleonitriledithiol

Him:

imidazole

Bz:

benzyl

py:

pyridine

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  1. State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, China

    Bei-sheng Kang, Mao-chun Hong, Ting-bin Wen, Han-qin Liu & Jia-xi Lu

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Kang, Bs., Hong, Mc., Wen, Tb. et al. Transition metal 1,2-bidentate thiolates as building blocks and their construction into cluster complexes. J Clust Sci 6, 379–401 (1995). https://doi.org/10.1007/BF01165468

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