Abstract
The electrolytic conductances of LiClO4, LiAsF6, NaClO4 and the n-butylammonium salts Bu4NCl, Bu4NClO4, and Bu4NBPh4 (tetraphenylborate) have been determined in dimethylsufite at 25°C. Ion association constants calculated from these data are interpreted in terms of solvent-separated ion pairs (for LiClO4, LiAsF6, and NaClO4), and contact ion pairs (for the n-butyl-ammonium salts). Comparisons are made for analogous electrolytes in acetone, and in which all salts form contact ion pairs.
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Plichta, E., Salomon, M., Slane, S. et al. Conductance and ion association in dimethylsulfite. J Solution Chem 15, 663–673 (1986). https://doi.org/10.1007/BF00644598
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DOI: https://doi.org/10.1007/BF00644598