Skip to main content
SpringerLink
Log in

13C-CP/MAS-NMR spectroscopy of tridentate diacidic ligands and their titanium(IV) chelates. molecular structure of bis[benzoylacetone thiobenzoylhydrazonato(2-)]titanium(iv)

  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

A series of tridentate diacidic ligands having the donor set ONO(S) as well as the corresponding titanium(IV) chelates were studied by13C-CP/MAS-NMR spectroscopy. Structural changes caused by the complex formation are discussed. The crystal structure of bis[benzoylacetone thiobenzo-ylhydrazonato(2-)]titanium(IV) was determined by X-ray analysis as to be distorted trigonal prismatic. Orthorhombic space group Pca2l,Z=4, 3304 observed independent reflections, unit-cell parameters at 298 K:a=22,808(2) å,b=13,073(4) å,c=10,450(4) å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Bayer, E.; Kneifel, H.Z. Naturforsch. 1972,27b, 207.

    Google Scholar 

  2. Carrondo, M. A. A. F. de C. T.; Duarte, M. T. L. S.; da Silva, J. J. R. F.; da Silva, J. A. L.Struct. Chem. 1992,3, 75.

    Google Scholar 

  3. Ludwig, E.; Hefele, H.; Uhlemann, E.; Weller, F.; KlÄui, W.Z. Anorg. Allg. Chem. 1995,621, 23.

    Google Scholar 

  4. Ludwig, E.; Hefele, H.; Friedrich, A.; Kallies, B.; Schilde, U.; Uhlemann, E.; Hahn, E.Z. Anorg. Allg. Chem. 1995,621, 488.

    Google Scholar 

  5. Hefele, H.; Ludwig, E.; Uhlemann, E.; Nöth, H.Z. Anorg. Allg. Chem. 1995,621, 1435.

    Google Scholar 

  6. Abildgaad, J.; Hansen, P. E.; Josephsen, J.; Lycka, A.Inorg. Chem. 1994,33, 5271.

    Google Scholar 

  7. Ludwig, E.; Hefele, H.; Schilde, U.; Uhlemann, E.Cryst. Res. Technol. 1994,29, 393.

    Google Scholar 

  8. Horvak, V.; Král, M.Coll. Czech. Chem. Commun. 1959,24, 564.

    Google Scholar 

  9. Bansse, W.; Ludwig, E.; Uhlemann, E.; Weller, F.; Dehnicke, K.; Herrmann, W.Z. Anorg. Allg. Chem. 1992,613, 36.

    Google Scholar 

  10. Diamantis, A. A.; Manikas, M.; Salam, M. A.; Snow, M. R.; Tiekink, E. R. T.Aust. J. Chem. 1988,41, 453.

    Google Scholar 

  11. Sheldrick, G. M. SHELXS-86, Program for the Solution of Crystal Structures; Göttingen, 1985.

  12. Sheldrick, G. M. SHELXL-93, Program for the Crystal Structure Refinement; Göttingen, 1993.

  13. Stoe + CIE GmbH 1994. Computer program X-step version 1.04.

  14. International Tables for X-Ray Crystallography, Vol. IV; Birmingham, 1974.

Download references

Author information

Authors and Affiliations

  1. Institut für Anorganische Chemie und Didaktik der Chemie, UniversitÄt Potsdam, D-14415, Potsdam, Germany

    H. Hefele, S. Sawusch, U. Schilde & E. Uhlemann

  2. Bundesanstalt für Materialforschung und -prüfung, D-12489, Berlin, Germany

    H. Jancke

Authors
  1. H. Hefele
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Jancke
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Sawusch
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. U. Schilde
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. Uhlemann
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hefele, H., Jancke, H., Sawusch, S. et al. 13C-CP/MAS-NMR spectroscopy of tridentate diacidic ligands and their titanium(IV) chelates. molecular structure of bis[benzoylacetone thiobenzoylhydrazonato(2-)]titanium(iv). Struct Chem 8, 211–216 (1997). https://doi.org/10.1007/BF02263509

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02263509

Key words

Search

Navigation