Summary
A detailed investigation has been made of the gravimetric determination of nickel with dimethylglyoxime in the presence of copper. Copper interference is eliminated by precipitation in a solution containing tartrate and thiosulphate at a pH of 5.5–6.5. The solubility of the nickel dimethylglyoxime complex has been determined as a function of temperature, pH and alcohol concentration.
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Claassen, A., Bastings, L. The gravimetric determination of nickel with dimethylglyoxime in the presence of copper. Z. Anal. Chem. 165, 354–360 (1959). https://doi.org/10.1007/BF00462358
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DOI: https://doi.org/10.1007/BF00462358