Accuracy of determination of trace metals in soil and sewage sludge

Abstract

Errors in the analysis of liquid samples are often large enough to be important. For solid materials, additional potential complications arise in separating the determinand from the sample matrix and in controlling possible interferences from co-extracted species. These considerations have led to the development of a stepwise, co-ordinated approach by which a group of laboratories have achieved predefined standards of accuracy. Sample digestion has been examined. The analysis of digests has then been addressed; the control of analytical precision has been emphasised. Finally, a demonstration of overall comparability has been undertaken. The results are presented.