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The influence of selected metals and halogens on the electronic system of benzoic acid

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Abstract

The influence of halogens and metals on the electronic system of the aromatic ring in lithium, sodium and potassium complexes with p-halogenobenzoic acids has been investigated by means of 13C and 1H NMR, IR and Raman spectroscopy and semi-empirical calculations. It has been shown that ionic potentials and electronegativities of halogens and metals are the main factors responsible for perturbations of the electronic charge distribution in the ring.

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Authors and Affiliations

  1. Institute of General Chemistry, Agricultural University of Warsaw, SGGW, Rakowiecka 26/30, 02-528, Warsaw, Poland

    W. Lewandowski, P. Koczon, P. Moscibroda & A. Orzechowska

  2. M.D. Anderson Centre, Department of Clinical Investigation, The University of Texas, Box 60 1515, Halcombe Blvd., Houston, TX, 77030, USA

    W. Priebe

Authors
  1. W. Lewandowski
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  2. W. Priebe
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  3. P. Koczon
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  4. P. Moscibroda
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  5. A. Orzechowska
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Lewandowski, W., Priebe, W., Koczon, P. et al. The influence of selected metals and halogens on the electronic system of benzoic acid. Fresenius J Anal Chem 355, 750–752 (1996). https://doi.org/10.1007/s0021663550750

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  • DOI: https://doi.org/10.1007/s0021663550750

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