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Dielectric constants of topaz, orthoclase and scapolite and the oxide additivity rule

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Abstract

The dielectric constants and dissipation factors of topaz, scapolite and orthoclase were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: topaz κ′ a =6.61 tan δ=0.0005 κ′ b =6.82 tan δ=0.0007 κ′ c =6.81 tan δ=0.0007 orthoclase κ′ a =4.69 tan δ=0.0007 κ′ b =5.79 tan δ=0.0007 κ′ c =5.63 tan δ=0.0011 κ′ 11 =4.72 κ′ 22 =5.79 κ′ 33 =5.76 scapolite κ′ a =6.74 tan δ=0.0004 κ′ c =8.51 tan δ=0.0004 The deviation (Δ) between measured dielectric polarizabilities as determined from the Clausius-Mosotti equation and those calculated from the sum of ion polarizabilities according to α D (mineral)=∑αD (ions) for topaz is 2.5%. The large deviations of orthoclase and scapolite from the oxide additivity rule with δ=+7.2 and + 17.6%, respectively, are attributed to “rattling” K ions in orthoclase and “rattling” (Na,K,Ca) ions and disordered O= and Cl- ions in scapolite.

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Authors and Affiliations

  1. Central Research and Development, Experimental Station 356/329, E.I. Du Pont de Nemours, 19880-0356, Wilmington, DE, USA

    Robert D. Shannon & Robert A. Oswald

  2. Division of Geological and Planetary Sciences, California Institute of Technology, 91125, Pasadena, CA, USA

    George R. Rossman

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  1. Robert D. Shannon
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  2. Robert A. Oswald
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  3. George R. Rossman
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Shannon, R.D., Oswald, R.A. & Rossman, G.R. Dielectric constants of topaz, orthoclase and scapolite and the oxide additivity rule. Phys Chem Minerals 19, 166–170 (1992). https://doi.org/10.1007/BF00202104

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  • DOI: https://doi.org/10.1007/BF00202104

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