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Synthesis of polyterephthalates derived from dianhydrohexitols

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Summary

By melting condensation of terephthalic acid dichloride and 1,4∶3,6-dianhydrohexitols as well as selectively prepared lower oligomers thereof the formation of polyterephthalates is achieved. These polyesters are characterized by 1H-NMR spectra vapour pressure osmometry (VPO), differential scanning calorimetry (DSC), viscosity measurements and combustion analyses. Their preparation and properties are discussed.

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Authors and Affiliations

  1. Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Orléans-Ring 23, D-4400, Münster

    Joachim Thiem

  2. Institut für Organisch Chemie and Biochemie, Universität Hamburg, Martin-Luther-King-Platz 6, D-2000, Hamburg 13, Germany

    Harald Lüders

Authors
  1. Joachim Thiem
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  2. Harald Lüders
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Additional information

Support of this work by the Fonds der Chemischen Industrie and Maizena Industrieprodukte GmbH, Hamburg is gratefully acknowledged.

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Thiem, J., Lüders, H. Synthesis of polyterephthalates derived from dianhydrohexitols. Polymer Bulletin 11, 365–369 (1984). https://doi.org/10.1007/BF00254275

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  • DOI: https://doi.org/10.1007/BF00254275

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