Summary
The kinetics of phase transition from the isotropic state to the nematic mesophase of a main-chain, thermotropic liquid crystalline polymer has been studied by DSC and optical microscopy. Avrami-type analysis of the data gives an exponent close to 1.0 which suggests nucleation followed by rod-like growth.
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Bhattacharya, S.K., Misra, A., Stein, R.S. et al. Kinetics of phase transition of a liquid crystalline polymer. Polymer Bulletin 16, 465–472 (1986). https://doi.org/10.1007/BF00955580
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DOI: https://doi.org/10.1007/BF00955580