Summary
A new kind of inorganic polymer containing no organic groups, silica-supported polystannazane (abbr. as Sn-N), and its Pd and Pt complexes (abbr. as Sn-N-Pd and Sn-N-Pt respectively) were synthesized. When these two complexes were used to catalyze the hydrogenation of nitro- and carbonyl-compounds and the compounds containing C=C double bound, it was found that they have higher catalytic activity at room temperature and under atmospheric hydrogen pressure. The hydrogenation of carbonyl-compounds can be controlled in the alcohol stage, no further hydrogenation happened.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Jiang, Y.Y.: Organic Chemistry, China, No.3, 25(1980)
Jiang, Y.Y.: Chemical Reagents, China, 129(1980)
Yuan, Y.X., Huang, M.Y. and Jiang, Y.Y.: Preprints of Symposium on Polymers, Hangzhou, 514(1983)
Yuan, Y.X., Huang, M.Y. and Jiang, Y.Y.: J. Macromol. Sci. -Chem., A24, 261(1987)
Huang, M.Y., Ren, C.Y. and Jiang, Y.Y.: J. Macromol. Sci. -Chem., A24, 269(1987)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Cao, S.K., Huang, M.Y. & Jiang, Y.Y. Hydrogenation catalyzed by silica-supported polystannazane-palladium and platinum complexes. Polymer Bulletin 19, 347–352 (1988). https://doi.org/10.1007/BF00263935
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00263935