Skip to main content
SpringerLink
Log in

Investigations on synthesis and characterization of carboxy-groups containing cellulose sulfates

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

Carboxymethyl cellulose and C-6-carboxy cellulose were treated with SO3 and HSO3CL in DMF yielding the corresponding watersoluble sulfate half-esters. A preferred sulfation of primary hydroxyl groups was found by 13C-n. m.r. spectroscopy. The potentiometric titration of the polyelectrolytes showed significant differences in the titration behaviour which can be explained by the different acidity of the carboxy groups in the two cellulose derivatives.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Heinze, D. Klemm, F. Loth and B. Philipp, Acta Polymerica 41, 259 (1990).

    Google Scholar 

  2. B. Philipp, H. Dautzenberg, K.-J. Linow, J. Kötz and W. Dawydoff, Progr. Polym. Sci. 14, 91 (1989)

    Google Scholar 

  3. R. A. A. Muzzarelli, F. Tafani, M. Emanuelli, D. P. Pace, E. Chiurazzi and M. Piani, Carbohydr. Res. 126, 225 (1984).

    Google Scholar 

  4. J. Kötz, B. Philipp, I. Nehls, T. Heinze and D. Klemm, Acta Polymerica 41 333 (1990).

    Google Scholar 

  5. K. Kamide, K. Okajima, K. Kowsaka, T. Matsui, S. Nomura and K. Hikichi, Polymer J. 17, 909, (1985).

    Google Scholar 

  6. B. Philipp, I. Nehls, W. Wagenknecht and M. Schnabelrauch, Carbohydr. Res. 164, 107 (1987).

    Google Scholar 

  7. L.T. Bach Tuyet, K. Iiyama and J. Nakano, Mokuzai Gakkaishi 31, 8 (1985).

    Google Scholar 

  8. D. Johnson, U. S. Pat. 3 447 939 (1969).

  9. T. Heinze, D. Klemm, F. Loth and I. Nehls, Angew. Makromol. Chem. 178, 95 (1990).

    Google Scholar 

  10. K. Niemelä and E. Sjöström, Polymer Commun. 30, 254 (1989).

    Google Scholar 

  11. A. Isogai, A. Ishizu and J. Nakano, Sen-I Gakkaishi 40, T-504 (1984).

Download references

Author information

Authors and Affiliations

  1. Institut für Organische Chemie und Makromolekulare Chemie der Friedrich-Schiller-Universität Jena, Humboldtstrasse 10, O-6900, Jena, Federal Republic of Germany

    M. Schnabelrauch, T. Heinze & D. Klemm

  2. Institut für Polymerenchemie “Erich Correns”, Kantstrasse 55, O-1530, Teltow-Seehof, Federal Republic of Germany

    I. Nehis & J. Kötz

Authors
  1. M. Schnabelrauch
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Heinze
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. Klemm
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. Nehis
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. Kötz
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Schnabelrauch, M., Heinze, T., Klemm, D. et al. Investigations on synthesis and characterization of carboxy-groups containing cellulose sulfates. Polymer Bulletin 27, 147–153 (1991). https://doi.org/10.1007/BF00296024

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00296024

Keywords

Search

Navigation