Summary
The novel dialkylanilinium salts of pentacoordinate Martin-type silicates were prepared. They were found to be air stable catalysts for polymerization of cyclohexene oxide. The preparation of those silicates bearing a bulky substituent such as mesityl group was not successful.
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Murakami, M., Ikai, S. & Yano, T. Effective catalysts for polymerization of cyclohexene oxide: Preparation of novel Martin-type pentacoordinate silicates. Polymer Bulletin 39, 573–579 (1997). https://doi.org/10.1007/s002890050188
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DOI: https://doi.org/10.1007/s002890050188