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Polymerization and copolymerization of vinyl carbamates and vinyl carbonates

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Abstract

Poly(vinyl carbamates) and poly(vinyl carbonates) of high molecular weight have been obtained by polymerization of the corresponding monomers prepared from vinyl chloroformate. Poly(vinyl carbonates) can also be prepared by chemical modification of poly(vinyl chloroformate) with alcohols and phenols. Copolymerization parameters of phenyl vinyl carbonate with vinyl acetate have been determined in methylene chloride, at 35°C, with dicyclohexyl peroxydicarbonate as initiator.

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Authors and Affiliations

  1. Laboratoire de Chimie Macromoléculaire Associé au CNRS, Collège de France, 11, Place Marcelin Berthelot, 75231, Paris Cedex 05, France

    Gilles Meunier & Patrick Hemery

  2. Centre de Recherche du Bouchet, SNPE, BP n∘2, 91710, Vert le Petit, France

    Jean -Pierre Senet & Sylvie Boileau

Authors
  1. Gilles Meunier
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  2. Patrick Hemery
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  3. Jean -Pierre Senet
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  4. Sylvie Boileau
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Meunier, G., Hemery, P., Senet, J.P. et al. Polymerization and copolymerization of vinyl carbamates and vinyl carbonates. Polymer Bulletin 4, 705–710 (1981). https://doi.org/10.1007/BF00285137

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  • DOI: https://doi.org/10.1007/BF00285137

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