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New phenothiazine-containing monomers and polymers

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Summary

Three new phenothiazine-containing electrono-donor monomers: methacryloyl-2′-hydroxyethyl-2-(N-phenothiazinyl)propionate (i) acryloyl-2′-hydroxyethyl-2-(N-phenothiazinyl) propionate (ii) and 2-(N-phenothiazinyl) propionic acid vinyl ester (iii) were synthesized and radically polymerized. The ionization potentials of poly(i), poly(iii) and of the model for the structural unit of the acrylic polymers: acetyl-2′-hydroxyethyl-2-(N-phenothiazinyl) propionate determined with two small acceptors were discussed in terms of sterical hindrances.

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Authors and Affiliations

  1. “Petru Poni” Institute of Macromolecular Chemistry, 6600, Jassy, Romania

    V. Percec, D. C. Tocaciu, E. Man & C. I. Simionescu

Authors
  1. V. Percec
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  2. D. C. Tocaciu
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  3. E. Man
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  4. C. I. Simionescu
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Percec, V., Tocaciu, D.C., Man, E. et al. New phenothiazine-containing monomers and polymers. Polymer Bulletin 5, 233–238 (1981). https://doi.org/10.1007/BF00265170

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  • DOI: https://doi.org/10.1007/BF00265170

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